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Temporal credit assignment is central to both biological and artificial intelligence, yet its interaction with non-linear function approximation is poorly understood. We identify a systematic failure mode in deep reinforcement learning (RL) termed Trace-Mediated Peak Bias (TMPB). At intermediate eligibility trace depths, agents irrationally prefer trajectories with high-magnitude reward ``peaks'' over alternatives with higher cumulative returns. This provides a mechanistic account of the Peak-End Rule: a human memory bias where experiences are judged by their most intense moments rather than integrated utility. We show that TMPB emerges because traces amplify distal Temporal Difference errors into ``gradient shocks'' that fixed-step-size Stochastic Gradient Descent cannot normalize, leading to global overestimation. Conversely, adaptive optimizers mitigate this pathology via second-moment normalization. Our results suggest that human-like saliency distortions may emerge naturally from the mathematical constraints of credit assignment in distributed systems, and that adaptive optimization is a theoretical necessity for rational value estimation.